State of Understanding of Nafion

Состояние представлений о Nafion
Robert B. Moore, Kenneth A. Mauritz
2004-09-21

Nafionfluoropolymersmembranesmorphologyscattering
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTState of Understanding of NafionKenneth A. Mauritz and Robert B. MooreView Author Information Department of Polymer Science, The University of Southern Mississippi, 118 College Drive #10076, Hattiesburg, Mississippi 39406-0001 Cite this: Chem. Rev. 2004, 104, 10, 4535–4586Publication Date (Web):September 21, 2004Publication History Received19 July 2004Published online21 September 2004Published inissue 1 October 2004https://pubs.acs.org/doi/10.1021/cr0207123https://doi.org/10.1021/cr0207123research-articleACS PublicationsCopyright © 2004 American Chemical SocietyRequest reuse permissionsArticle Views41738Altmetric-Citations3971LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Cluster chemistry,Fluoropolymers,Membranes,Morphology,Scattering Get e-Alerts
1
Despite extensive study (reflected by high citation and attention metrics), key aspects of Nafion morphology and function remain unresolved, motivating further research.
2
Nafion's morphology and microstructure have been extensively characterized using scattering techniques, informing models of ionic clusters and channels.
3
The literature up to 2004 presents competing models for Nafion's ionic domain organization, reflecting incomplete consensus on cluster size, shape, and connectivity.
4
The review synthesizes the state of understanding of Nafion, covering cluster chemistry, fluoropolymer structure, membrane morphology, and scattering studies.
5
Understanding of Nafion links its fluoropolymer backbone and sulfonic acid groups to membrane transport properties, highlighting structure–property relationships critical for applications.

Nafion membrane (perfluorosulfonic acid polymer)

State of understanding of Nafion's structure–property relationships, morphology, phase behavior, ionic conduction mechanisms, and scattering-characterized microstructure

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2004-09-21
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Robert B. Moore
Kenneth A. Mauritz
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