<i>CelluPhot</i>: Hybrid Cellulose−Bismuth Oxybromide Membrane for Pollutant Removal

CelluPhot: гибридная мембрана из целлюлозы и оксибромида висмута для удаления загрязнителей
Joy Onwumere, Jędrzej Piątek, Tetyana M. Budnyak, Jianhong Chen, Serhiy Budnyk, Zoheb Karim, Thomas Thersleff, Piotr Kuśtrowski, Aji P. Mathew, Adam Slabon
2020-08-25

Bioinorganic interfaceCellulose–bismuth oxybromide membraneCo(II) and Ni(II) ion adsorptionPhotocatalytic degradationRhodamine B removal
/BiOBr showed higher affinity to Co(II) ions than to Ni(II) ions from diluted aqueous solutions. The bioinorganic composite demonstrates a synergistic effect in the photocatalytic degradation of rhodamine B (RhB) by exceeding the removal efficiency of single components. The fabrication of the biologic-inorganic interface was confirmed by various analytical techniques including scanning electron microscopy (SEM), scanning transmission electron microscopy with energy dispersive X-ray spectroscopy (STEM EDX) mapping, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The presented approach for controlled formation of the bioinorganic interface between natural material (cellulose) and nanoscopic inorganic materials of tailored morphology (Bi-O-Br system) enables the significant enhancement of materials functionality.
1
Controlled integration of cellulose with nanoscopic Bi–O–Br materials of tailored morphology significantly enhances the composite’s functionality for pollutant removal.
2
SEM, STEM–EDX mapping, XRD, and XPS confirmed formation of the cellulose–BiOBr biologic–inorganic interface.
3
The cellulose–BiOBr bioinorganic composite exhibits selective adsorption, showing higher affinity for Co(II) than Ni(II) in diluted aqueous solutions.
4
The composite produces a synergistic photocatalytic effect for rhodamine B degradation, exceeding the removal efficiency of cellulose and BiOBr components alone.

Cellulose–bismuth oxybromide (BiOBr) hybrid membrane

Pollutant-removal performance, including Co(II)/Ni(II) ion affinity and synergistic photocatalytic degradation of rhodamine B

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2020-08-25
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Joy Onwumere
Jędrzej Piątek
Tetyana M. Budnyak
Jianhong Chen
Serhiy Budnyk
Zoheb Karim
Thomas Thersleff
Piotr Kuśtrowski
Aji P. Mathew
Adam Slabon
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