2021 roadmap for sodium-ion batteries

Дорожная карта развития натрий-ионных аккумуляторов на 2021 год
Manish Chhowalla, Russell E. Morris, Aamod V. Desai, A. Robert Armstrong, Maria‐Magdalena Titirici, Clare P. Grey, Philippe Poizot, Stéven Renault, Christopher I. Thomas, Robert G. Palgrave, Emma Kendrick, William I. F. David, Patrik Johansson, Reza Younesi, Andrew J. Naylor, David O. Scanlon, Ronnie Mogensen, Moulay Tahar Sougrati, John M. Griffin, John T. S. Irvine, Oleg Kolosov, Ashish Rudola, Heather Au, Emily Reynolds, Jincheng Tong, Nuria Tapia‐Ruiz, Yue Chen, Christopher A. O’Keefe, Hande Alptekin, Maria Crespo Ribadeneyra, Ruth Sayers, J. Barker, Begoña Silván, Edmund J. Cussen, Serena A. Cussen, Martin O. Jones, Laure Monconduit, Marco Amores, R.C. Boston, William R. Brant, Jake M. Brittain, Yong‐Seok Choi, Sara I R Costa, Stewart A M Dickson, E.I. Eweka, Juan Forero‐Saboya, Peter Groß, Xiao Hua, Martin Karlsmo, Eun Jeong Kim, Zhuangnan Li, Stijn F. L. Mertens, Shahin Nikman, Darren M. C. Ould, Alexandre Ponrouch, Sudeshna Sen, Valerie R. Seymour, Lorenzo Stievano, Grant S Stone, Thomas J. Wood, Dominic S. Wright
2021-07-01

lithium-ion batterieslow-cost vehiclessodium-ion batteriessolid–electrolyte interphasestationary energy storage
Abstract Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
1
Distinct sodium and lithium physicochemical properties produce different coordination, desolvation, and solid–electrolyte interphase behaviors, requiring dedicated fundamental studies.
2
Limited lithium availability, expected price increases, and concerns over transition-metal sourcing are driving industrial and research investment in sodium-ion batteries.
3
Sodium-ion batteries are positioned as sustainable alternatives to lithium-ion batteries because sodium is abundant, cost-effective, and has a lithium-like redox potential.
4
Sodium-ion technology could support stationary energy storage and low-cost vehicles, while benefiting from potential compatibility with existing lithium-ion manufacturing infrastructure.
5
The 2021 roadmap reviews the field’s state of the art and identifies research strategies for improving sodium-ion battery performance from laboratory development through scale-up.

sodium-ion batteries

the underlying physicochemical processes, performance improvement, and application development of sodium-ion batteries

Publication Details
Publication Date
2021-07-01
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Cited by
279
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Authors
Manish Chhowalla
Russell E. Morris
Aamod V. Desai
A. Robert Armstrong
Maria‐Magdalena Titirici
Clare P. Grey
Philippe Poizot
Stéven Renault
Christopher I. Thomas
Robert G. Palgrave
Emma Kendrick
William I. F. David
Patrik Johansson
Reza Younesi
Andrew J. Naylor
David O. Scanlon
Ronnie Mogensen
Moulay Tahar Sougrati
John M. Griffin
John T. S. Irvine
Oleg Kolosov
Ashish Rudola
Heather Au
Emily Reynolds
Jincheng Tong
Nuria Tapia‐Ruiz
Yue Chen
Christopher A. O’Keefe
Hande Alptekin
Maria Crespo Ribadeneyra
Ruth Sayers
J. Barker
Begoña Silván
Edmund J. Cussen
Serena A. Cussen
Martin O. Jones
Laure Monconduit
Marco Amores
R.C. Boston
William R. Brant
Jake M. Brittain
Yong‐Seok Choi
Sara I R Costa
Stewart A M Dickson
E.I. Eweka
Juan Forero‐Saboya
Peter Groß
Xiao Hua
Martin Karlsmo
Eun Jeong Kim
Zhuangnan Li
Stijn F. L. Mertens
Shahin Nikman
Darren M. C. Ould
Alexandre Ponrouch
Sudeshna Sen
Valerie R. Seymour
Lorenzo Stievano
Grant S Stone
Thomas J. Wood
Dominic S. Wright
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