Study of proximity lithography simulations using measurements of dissolution rate and calculation of the light intensity distributions in the photoresist

Исследование моделирования приближённой литографии с использованием измерений скорости растворения и расчёта распределений интенсивности света в фоторезисте
Atsushi Sekiguchi, Toshiharu Matsuzawa, Yoshihisa Sensu, Mariko Isono, Mikio Kadoi
2004-05-14

Hopkins equationSEM verificationVan Cittert-Zernike theorybroadband 350 nm–450 nm illuminationdiazonaphthoquinone (DNQ)-novolak resistdissolution rate measurementgap effectlight intensity distributionproximity lithographyresist profile simulation
This report describes the results of a study on resist profile simulation in proximity printing, using light intensity distribution and actually measured dissolution rate values, a method that takes the gap effect into consideration (the effect of the distance between mask and wafer on the aerial image and resist profiles). We calculate the light intensity distribution with the gap effect based on the Van Cittert-Zernike theory and on the Hopkins equation as a model of light intensity distribution of proximity printing in resist film. Dissolution rate values are obtained using an apparatus to measure resist film thickness during development. The resist profile simulation is carried out using the combined data thus obtained. To verify the validity of this simulation, we use an SEM to observe resist profiles obtained from a diazonaphthoquinone (DNQ)-novolak resin positive-type resist for thick films, varying the proximity gaps using the mask aligner, which uses light in the broadband wavelengths of 350 mm to 450 mm, and compare the results with the simulation. The results of simulation and those of the SEM observation are in agreement, proving the validity of our method.
1
A resist profile simulation method for proximity printing was developed that incorporates gap effects using light intensity distributions and measured dissolution rates.
2
Dissolution rate values for the resist were experimentally measured during development using an apparatus that monitors resist film thickness.
3
Light intensity distribution in the photoresist including gap effects was modeled using Van Cittert-Zernike theory combined with the Hopkins equation.
4
Simulated resist profiles using the combined light-intensity and measured dissolution-rate data agree with SEM-observed profiles for DNQ-novolak positive resist under varied proximity gaps.
5
Validation was performed for thick resist films exposed with broadband light (350 nm–450 nm) on a mask aligner, demonstrating the method's accuracy in accounting for mask-wafer gap effects.

Proximity printing resist system comprising mask, gap (mask‑wafer distance), photoresist film (DNQ‑novolak positive thick resist), and resulting resist profiles

Simulation and verification of resist profile formation accounting for gap‑dependent aerial light intensity distributions (Van Cittert‑Zernike and Hopkins models) and measured resist dissolution rates

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2004-05-14
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Authors
Atsushi Sekiguchi
Toshiharu Matsuzawa
Yoshihisa Sensu
Mariko Isono
Mikio Kadoi
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