A regioselective step-by-step C<sub>60</sub>Cl<sub>6</sub> functionalization approach affords a novel family of C<sub>60</sub>Ar<sub>5</sub>Th′Th′′H fullerene derivatives with promising antiviral properties
Региоизбирательный пошаговый подход к функционализации C60Cl6 позволяет получить новую семью производных фуллерена C60Ar5Th′Th′′H с перспективными противовирусными свойствами
2023-01-01
SCID: 54.1/77tca7un
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C60Ar5Th'Th''H fullerene derivativesC60Cl6 functionalizationantiviral and antioxidant fullerene propertiesregioselective step-by-step functionalizationthiophene derivatives (Th''H) reaction
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Abstract (AI)
We report a novel reaction of the recently discovered family of fullerene derivatives <i>C</i><sub>1</sub>-C<sub>60</sub>Ar<sub>5</sub>Th' with thiophene derivatives Th''H yielding a previously unknown family of <i>C</i><sub>1</sub>-C<sub>60</sub>Ar<sub>5</sub>Th'Th''H compounds with three different types of functional aromatic addends attached to the carbon cage. The discovered reaction paves a way to the synthesis of novel C<sub>60</sub> fullerene derivatives with promising antioxidant and antiviral properties.
Key Findings
1
A novel reaction transforms C1-C60Ar5Th' fullerene derivatives with thiophene derivatives Th''H into previously unknown C1-C60Ar5Th'Th''H compounds.
2
The discovered regioselective, step-by-step C60Cl6 functionalization approach enables synthesis of these novel fullerene derivatives.
3
The new compounds feature three different types of functional aromatic addends attached to the C60 carbon cage.
4
The synthesized C1-C60Ar5Th'Th''H fullerene derivatives show promising antioxidant and antiviral properties.
Research Object
Novel C60 fullerene derivatives of the C1-C60Ar5Th'Th''H family (fullerene carbon cage functionalized with three different aromatic addends including Ar and thiophene units)
Research Subject
Regioselective step-by-step C60Cl6 functionalization reaction pathway and resulting structural diversification leading to antioxidant and antiviral properties of the C1-C60Ar5Th'Th''H derivatives
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2023-01-01
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