Hydroformylation of Internal Olefins to Linear Aldehydes with Novel Rhodium Catalysts

Piet W. N. M. van Leeuwen, Paul C. J. Kamer, Lars A. van der Veen
1999-02-01

SCID:  54.1/7d25mmed
Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.
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1999-02-01
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Piet W. N. M. van Leeuwen
Paul C. J. Kamer
Lars A. van der Veen
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