Hydroformylation of Internal Olefins to Linear Aldehydes with Novel Rhodium Catalysts
1999-02-01
SCID: 54.1/7d25mmed
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Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.
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1999-02-01
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