Onboard Carbon Capture for Circular Marine Fuels

Улавливание углерода на борту судна для производства замкнутых морских топливных циклов
Margarita A. Charalambous, Valentina Negri, Valentin Kamm, Gonzalo Guillén‐Gosálbez
2025-02-04

carbon capture and utilizationchemical absorptioncircular marine fuelselectrolytic hydrogenonboard carbon capture
High Resolution Image Download MS PowerPoint Slide The transition to low- and zero-carbon fuels is the primary driver for reducing emissions in the maritime industry, with methanol and natural gas emerging as the most promising options. However, carbon-based fuels will continue to emit considerable amounts of pollutants during their use phase. This work explores the application of circular economy principles in the shipping industry by integrating carbon capture and utilization technologies. Specifically, we propose a closed-loop system where carbon dioxide (CO 2 ) generated onboard is captured using a chemical absorption technology and stored until the ship reaches a port. The captured CO 2 is then unloaded and transported to a fuel production facility, where it reacts with electrolytic hydrogen to regenerate the required propulsion fuel. Here, we evaluate the economic, technical, and future environmental viability of methanol and natural gas as circular marine fuels. Our findings indicate that natural gas could achieve a 65% reduction in CO 2 emissions by 2050, while methanol could lead to 55%, both with a 91% carbon capture rate. However, there is an economic premium of 339 USD tonCO 2 –1 for methanol and 260 USD tonCO 2 –1 for natural gas. Additionally, the shift to circular fuels is expected to increase costs by a factor of 3–6 compared to conventional operations.
1
Chemical absorption is used to capture onboard CO₂, enabling circular production of methanol and natural gas for shipping.
2
Circular marine fuels carry economic premiums of 339 USD tonCO₂⁻¹ for methanol and 260 USD tonCO₂⁻¹ for natural gas.
3
Switching from conventional operations to circular fuels is expected to increase costs by a factor of 3–6, despite future environmental benefits.
4
The paper proposes a closed-loop marine fuel system capturing onboard CO₂, transporting it to port, and converting it with electrolytic hydrogen into propulsion fuel.
5
With a 91% carbon capture rate, circular natural gas could reduce CO₂ emissions by 65% by 2050, compared with 55% for methanol.

closed-loop onboard carbon capture and utilization systems for methanol- and natural-gas-fueled ships

the economic, technical, and future environmental viability of producing circular marine fuels from captured onboard CO2 and electrolytic hydrogen

Publication Details
Publication Date
2025-02-04
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Authors
Margarita A. Charalambous
Valentina Negri
Valentin Kamm
Gonzalo Guillén‐Gosálbez
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