Hexakis(<i>N</i>,<i>N</i>-dimethylformamide-<i>O</i>)nickel(II) Bis(tetrafluoroborate)
Гексахис(N,N-диметилформамид-O)никель(II) бис(тетрафтороборат)
1998-03-15
SCID: 54.1/9hfn68pd
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BF4− anion[Ni(dmf)6]2+hexakis(N,N-dimethylformamide-O)nickel(II)hydrogen-bonding interactionspolymeric chains
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Abstract (AI)
In the title compound, [Ni(C3H7NO)6](BF4)2, there are two independent [Ni(dmf)6]2+ cations, each with a crystallographically imposed centre of symmetry. Hydrogen-bonding interactions between the cations and BF4− anions allow the formation of polymeric chains.
Key Findings
1
Hydrogen-bonding interactions between the [Ni(dmf)6]2+ cations and BF4− anions organize the structure into polymeric chains.
2
The crystal structure of [Ni(C3H7NO)6](BF4)2 consists of two independent [Ni(dmf)6]2+ cations, each located on a crystallographic center of symmetry.
3
The title compound is hexakis(N,N-dimethylformamide-O)nickel(II) with two BF4− counteranions per formula unit.
Research Object
[Ni(C3H7NO)6](BF4)2 (hexakis(N,N-dimethylformamide-O)nickel(II) bis(tetrafluoroborate))
Research Subject
Crystal structure and supramolecular assembly characterized by two independent centrosymmetric [Ni(dmf)6]2+ cations and hydrogen-bonding interactions with BF4− leading to polymeric chain formation
Publication Details
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1998-03-15
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