Evaluation of the migration and environmental effects of metal elements within cementitious gangue-fly ash backfill in underground coal mines

Оценка миграции и воздействия металлических элементов на окружающую среду в цементированном закладочном материале из пустой породы и летучей золы в подземных угольных шахтах
Xuejie Deng, Jiao Yuan, Shicong Li, Nan Zhou, Yan An, Erol Yilmaz, Qingxue Zheng, Xifeng Liang
2024-11-01

cementitious gangue-fly ash backfillenhanced Nemerow indexgroundwater pollutionmetal element migrationstress-permeability-concentration coupling
Cementitious gangue-fly ash backfill (CGB) is used as a green mining technology worldwide. However, under the coupled effects of geological stress and groundwater, the metal elements in the CGB tend to migrate into nearby strata, which can consequently result in pollution of the groundwater environment. In this paper, the influence of initial pH and stress damage on the migration behavior of metal elements in CGB is quantitatively studied through the multi-physical field coupling model of stress-permeability-concentration. The enhanced Nemerow index evaluation method is used to comprehensively evaluate the impact of these metal elements migration behaviors on the groundwater environment. The research results show that: (1) When the stress damage of the CGB increases from 0.76 to 0.95, the Darcy velocity at the bottom of the CGB first increases, then decreases, and finally stabilizes at 2.01×10 −7 m/s. The longest time to reach the maximum Darcy velocity is 3 a. (2) When the damage of the CGB is 0.95, the farthest migration distances of Al, Cr, Mn, Fe, Ba, and Pb are 40.5, 34.0, 29.8, 32.9, 38.8 and 32.1 m, respectively. (3) The alkaline environment stimulates the migration of Al, Cr, Fe, Mn, and Pb, whereas Ba migrates farther under acidic conditions. The farthest migration distance of Ba is 31.6 m under pH 3. (4) The enhanced Nemerow index indicates that when stress damage increases from 0.76 to 0.95, the areas with poor water quality increase from 0 to 1.71%, and no area is classified as very poor grade. When the initial pH changes from 3 to 11, 100% of the region is classified as fair or above. The initial pH of the CGB has a relatively slight influence on the groundwater environment. This study provides experimental data and theoretical basis for the environmental evaluation of CGB.
1
A coupled stress–permeability–concentration model quantitatively evaluates how initial pH and stress damage control metal migration from cementitious gangue-fly ash backfill.
2
Alkaline conditions enhance Al, Cr, Fe, Mn, and Pb migration, whereas Ba migrates farther in acidic conditions, reaching 31.6 m at pH 3.
3
As CGB stress damage increases from 0.76 to 0.95, bottom Darcy velocity initially rises, then declines and stabilizes at 2.01×10−7 m/s; the maximum may take 3 years to occur.
4
At damage 0.95, maximum migration distances are 40.5 m for Al, 34.0 m for Cr, 29.8 m for Mn, 32.9 m for Fe, 38.8 m for Ba, and 32.1 m for Pb.
5
Increasing stress damage from 0.76 to 0.95 raises poor-groundwater-quality areas from 0 to 1.71%, while pH changes from 3 to 11 leave 100% of the region classified as fair quality or better, indicating relatively limited pH effects.

Cementitious gangue-fly ash backfill (CGB) in underground coal mines and the surrounding groundwater environment

Metal-element migration behavior in CGB under coupled geological stress, stress damage, groundwater permeability, and initial pH, and its impact on groundwater quality

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2024-11-01
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Xuejie Deng
Jiao Yuan
Shicong Li
Nan Zhou
Yan An
Erol Yilmaz
Qingxue Zheng
Xifeng Liang
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