Simultaneous degumming and deacidification of crude palm oil using mixed matrix PVDF membrane

Одновременная дегуммизация и деацидификация сырого пальмового масла с использованием поливинилиденфторидной мембраны с матричным наполнителем
Nur Hidayati Othman, R. Latip, Ahmadilfitri Mohd. Noor, W.J. Lau, Pei Sean Goh, Ahmad Fauzi Ismail
2021-10-01

PVDF membranecrude palm oilmagnesium silicatemixed matrix membranesimultaneous degumming and deacidification
Abstract The research work aimed to investigate the compatibility of polyvinylidene difluoride (PVDF) membrane embedded with various inorganic adsorbents for producing a mixed matrix membrane (MMM) and to examine the capability of mixed matrix PVDF membrane (PVDF-MMM) for simultaneous degumming and deacidification of crude palm oil (CPO). Four different adsorbent were tested which includes calcium silicate (CaS), magnesium silicate (MagS), ZSM-zeolite (ZSM) and activated carbon (AC). The in-house made PVDF-MMM was fabricated according to the dry-jet wet spinning method. The performances of these PVDF-MMMs were assessed with respect to the removals of phosphorus, FFA and colour. Based on finding showed that the combination of 18PVDF embedded with 3 wt% MagS showed the most compatible polymer-inorganic hybrid MMM to perform pre-treatment of CPO. Increasing the MagS concentration from 3 to 8 wt% in the polymer matrix recorded the highest removals of FFA at 16.51 %, phospholipid at 93.31 % and colour at 18.8 %, respectively. Nevertheless, high amount of MagS added to the polymer matrix affected the spinnability and reproducibility performance of MMM. Future work, surface modifications of inorganic adsorbent can be evaluated to facilitate good dispersion of filler in polymer matrix during membrane fabrication to maintain good membrane reproducibility.
1
An 18% PVDF membrane containing 3 wt% magnesium silicate showed the best polymer–inorganic compatibility for crude palm oil pretreatment.
2
High magnesium silicate loading impaired membrane spinnability and reproducibility, indicating a trade-off between removal performance and fabrication quality.
3
Increasing magnesium silicate loading from 3 to 8 wt% produced maximum removals of 16.51% FFA, 93.31% phospholipids, and 18.8% colour.
4
PVDF mixed matrix membranes embedded with calcium silicate, magnesium silicate, ZSM-zeolite, or activated carbon were investigated for simultaneous degumming and deacidification of crude palm oil.
5
Surface modification of inorganic adsorbents was identified as a potential strategy to improve filler dispersion and membrane reproducibility.

mixed matrix polyvinylidene difluoride (PVDF) membranes embedded with inorganic adsorbents for treating crude palm oil

the compatibility, spinnability, reproducibility, and simultaneous degumming and deacidification performance of PVDF mixed matrix membranes, measured by phosphorus, phospholipid, free fatty acid, and colour removal

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Publication Date
2021-10-01
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Nur Hidayati Othman
R. Latip
Ahmadilfitri Mohd. Noor
W.J. Lau
Pei Sean Goh
Ahmad Fauzi Ismail
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