ChemInform Abstract: Structural Modulation of Anionic Group Architectures by Cations to Optimize SHG Effects: A Facile Route to New NLO Materials in the ATCO3F (A: K, Rb; T: Zn, Cd) Series.
ChemInform: Структурная модуляция архитектур анионных групп катионами для оптимизации эффектов генерации второй гармоники: простой способ получения новых нелинейно-оптических материалов ряда ATCO3F (A: K, Rb; T: Zn, Cd).
2016-01-01
SCID: 54.1/akhk3bcv
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ATCO3F seriesnonlinear optical materialssecond-harmonic generationstructural modulationsubcritical hydrothermal synthesis
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Abstract (AI)
Abstract Crystals of KCdCO3F (I), RbCdCO3F (II), KZnCO3F (III), and RbZnCO3F (IV) are grown under subcritical hydrothermal conditions, using e.g. a 1:6:2 molar mixture of CdCl2, KF, and K2CO3 in H2O for KCdCO3F (autoclave, 220 °C, 5 d).
Key Findings
1
Four ATCO3F-series crystals—KCdCO3F, RbCdCO3F, KZnCO3F, and RbZnCO3F—were synthesized.
2
KCdCO3F synthesis used a 1:6:2 molar mixture of CdCl2, KF, and K2CO3 in water.
3
KCdCO3F was obtained hydrothermally at 220 °C over five days in an autoclave.
4
The crystals were grown under subcritical hydrothermal conditions.
Research Object
ATCO3F (A = K, Rb; T = Zn, Cd) crystals, specifically KCdCO3F, RbCdCO3F, KZnCO3F, and RbZnCO3F
Research Subject
Structural modulation of anionic group architectures by cations to optimize second-harmonic generation (SHG) effects and develop new nonlinear-optical (NLO) materials
Publication Details
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2016-01-01
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