9.14.5 Phospholes (Update 2024)
9.14.5 Фосфолы (обновление 2024)
2023-12-22
SCID: 54.1/eghve5bc
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1H-phospholes5-phospholyl complexeslow aromaticityphospholide ionssubstituted 1H-phospholes synthesis
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Abstract (AI)
Abstract 1H-Phospholes are five-membered heterocyclic compounds with a low degree of aromaticity. The low aromaticity of 1H-phospholes makes them a unique motif in terms of their applications in materials chemistry. On the other hand, 1H-phospholes have reactivity that contrasts with that of other five-membered heterocyclic compounds, such as furans, pyrroles, and thiophenes. This review summarizes procedures used for the preparation of substituted 1H-phospholes in the period 2012–2023. In addition, the synthesis of phospholide ions and (5-phospholyl complexes is described.
Key Findings
1
1H-Phospholes are five-membered heterocycles characterized by a low degree of aromaticity, distinguishing them from related heterocycles.
2
1H-Phospholes exhibit reactivity patterns that contrast with furans, pyrroles, and thiophenes.
3
The low aromaticity of 1H-phospholes makes them especially valuable for applications in materials chemistry.
4
The review also summarizes methods for synthesizing phospholide ions and 5-phospholyl complexes.
5
The review compiles synthetic procedures for substituted 1H-phospholes reported between 2012 and 2023.
Research Object
1H-phospholes (substituted 1H-phosphole compounds, phospholide ions, and 5-phospholyl complexes)
Research Subject
Synthetic procedures and methods for preparation (2012–2023) of substituted 1H-phospholes, and synthesis of phospholide ions and 5-phospholyl complexes
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2023-12-22
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