Ab initio methodsAbnormal NHC catalystAcceptor-less dehydrogenationbond dissociation energiessubject index
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Abstract (AI)
A A1 mechanism, hydrolysis with, 73-4 A2 mechanism, hydrolysis with, 73-4, 82 Abietadienyl cation, 297 Ab initio methods, 38 alkene reactions, facial selectivities, 372 anomeric effect studies, 202 bond dissociation energies, 186 carbene addition to CO, 209 decarbonylation, of aldehydes, 364 electrophilic additions, 375-6 gas-phase reactions, 185, 375-6 halogen/hydrohalide reactions, 203 hydrolysis, 85-6 Kirby's model for enzymes, 376 nucleophilic additions, 402-3 oxidation of 6-methyluracil, 154 Abnormal NHC catalyst, 224 Acceptor-less dehydrogenation, 150 ACE computational program, 97 Acetaldehyde, 376 oxidation of, 105-6 Wittig reaction of, 365 Acetals, 2-3 in Au-mediated rearrangements, 516 benzylidene-type, 159 photosensitive, formation of, 150 reductive ring opening of, 159 Acetanilides, formation of, 271 Acetates, hydrogenation of, 178 Acetic acid catalyst, 159 Acetone, 376 mono-α-arylation of, 340 oxidation of, 113 Acetonitrile epoxidation with, 117 oxidative cross-coupling, 125 Acetophenone, 142 transfer hydrogenation of, 117 Acetophenones p-substituted, oxidation of, 128 in triarylpyridine synthesis, 150-1 α-Acetoxy aldehydes, synthesis of, 150 α-Acetoxy β-amino acid derivatives, 187 α-Acetoxy-β-enamino esters, 187
Key Findings
1
A range of functional group transformations are covered: acetals formation and photosensitivity, reductive ring opening, α-acetoxy aldehyde synthesis, and α-acetoxy β-amino/β-enamino derivatives.
2
Ab initio methods are applied to studies including alkene reactions, anomeric effects, and bond dissociation energies.
3
Hydrolysis mechanisms A1 and A2 are discussed, with page references indicating comparative coverage (pages 73-74, 82).
4
Oxidation and decarbonylation reactions of aldehydes and ketones (e.g., acetaldehyde, acetone, acetophenone) are indexed with specific page references.
5
Specific catalytic and mechanistic topics are indexed: abnormal NHC catalysts, acceptor-less dehydrogenation, Au-mediated rearrangements, and ACE computational program.
6
The document is a comprehensive subject index covering diverse chemical topics and methods across many pages.
Research Object
Subject index of a chemistry text (list of chemical species, reactions, mechanisms, and topics)
Research Subject
Organization and indexing of chemical topics and entries (species, reaction types, mechanisms, methods, and page references) within the book
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2014-04-04
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