“Condensative Chain Polymerization”—A Way Towards “Living” Polycondensation?
«Конденсационная цепная полимеризация» — путь к «живой» поликонденсации?
2000-10-02
SCID: 54.1/euvgtqn9
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Condensative Chain Polymerizationcontrol of molar mass and molar mass distributionliving polycondensationphase-transfer catalysispolycondensation
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Abstract (AI)
Although not a revolution in the area of classical polycondensation, many new ideas for this area can be expected to result from the work of Yokozawa and Suzuki described here. By skillful use of the ideas of phase-transfer catalysis they have succeeded in controlling the molar mass, the molar mass distribution, and the polymer end groups.
Key Findings
1
Application of phase-transfer catalysis concepts enables control over molar mass in condensative chain polymerization.
2
Phase-transfer catalysis methods allow control of molar mass distribution during polycondensation.
3
The approach permits control over polymer end groups in condensative chain polymerization.
4
The work by Yokozawa and Suzuki introduces new ideas that advance classical polycondensation toward more controlled ('living') behavior.
Research Object
Condensative chain polymerization process for polycondensation (as implemented by Yokozawa and Suzuki)
Research Subject
Control of polymer molar mass, molar mass distribution, and polymer end groups via phase-transfer catalysis to achieve ‘living’ polycondensation-like behavior
Publication Details
Publication Date
2000-10-02
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