Simulation of Anti-Reflective TiO2/SiO2 Coating for Silicon Photovoltaic Application by Ray Tracing

Моделирование просветляющего покрытия TiO2/SiO2 для применения в кремниевой фотоэлектрике методом трассировки лучей
S.H.S. Salleh
2023-03-17

TiO2/SiO2 multilayeranti-reflective coatingphotocurrent densityray-tracing simulationsilicon solar cells
n solar systems, anti-reflective coatings are used to reduce reflection and increase efficiency. However, the front surface on the solar cells alone is not effective because most of the light from the sun is reflected and very less energy absorption into the solar cells occur. An anti-reflective coating (ARC) of a sufficient thickness can greatly reduce front surface reflectance. Nanoscale surface texturing, on the other hand, can efficiently capture a higher ratio of incident light to boost optical absorption. In this study, the light trapping scheme within the wavelength of 300 to 1200 nm was used to improve the overall efficiency of silicon solar cells. A thin layer of TiO2 and SiO2 anti-reflective coating with different thicknesses was stacked alternatingly due to their different refractive index with TiO2 having a high refractive index and SiO2 with a low refractive index. Solar irradiance spectrum AM1.5G at normal incidence was used in this present work. For the ray-tracing simulation, the front planar with multilayer ARC with different thicknesses were investigated to obtain the optimum value for optical properties and current density. All the four combination arrangements of SiO2 and TiO2 were evaluated and the maximum potential photocurrent density (Jmax) was calculated. The Jmax value of thin crystalline silicon, c-Si (without ARC) was 24.93 mA/cm2 and increased to 30.28 mA/cm2when ARC was used on the front surface. This represents an increasing of 21.46 % enhancement compared to the Jmax of the c-Si reference. Simulation of Anti-Reflective TiO2/SiO2 Coating for Silicon Photovoltaic Application by Ray TracingImran Al-Haqeem Bin Jaffar1, Siti Hajar Mohmad Salleh2*, Mohd Zaki Mohd Yusoff31,2Faculty of Applied Sciences, Universiti Teknologi MARA, Cawangan Perlis, Campus Arau, 02600 Perlis, Malaysia3Faculty of Applied Science, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia*Corresponding author’s E-mail: sitiha2902@uitm.edu.myReceived: 08 August 2022 Accepted: 17 February 2023Online First: 17 March 2023
1
A ray-tracing study evaluated alternating TiO2/SiO2 multilayer anti-reflective coatings for silicon solar cells across 300–1200 nm under AM1.5G normal-incidence illumination.
2
The coating produced a 21.46% enhancement in maximum potential photocurrent density relative to the uncoated crystalline-silicon reference.
3
The optimized anti-reflective coating increased maximum potential photocurrent density from 24.93 mA/cm² for uncoated crystalline silicon to 30.28 mA/cm².
4
The simulations compared four TiO2/SiO2 layer arrangements and thicknesses to optimize front-surface optical properties and potential photocurrent density.
5
The study combines multilayer refractive-index engineering with nanoscale light-trapping considerations to reduce reflection and improve silicon-cell absorption.

Front-planar crystalline silicon solar cells with alternating multilayer TiO2/SiO2 anti-reflective coatings

Wavelength-dependent light trapping, optical reflectance, absorption, and maximum photocurrent density of the multilayer anti-reflective coatings under AM1.5G illumination

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2023-03-17
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S.H.S. Salleh
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