Nucleophilic Substitution Reactions by Electron Transfer
Реакции нуклеофильного замещения посредством переноса электрона
2002-12-12
SCID: 54.1/hhtm328j
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anion reactionselectron transferhalogen substratesnucleophilic substitutionreaction mechanisms
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNucleophilic Substitution Reactions by Electron TransferRoberto A. Rossi, Adriana B. Pierini, and Alicia B. PeñéñoryView Author Information INFIQC, Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, 5000 Córdoba, Argentina Cite this: Chem. Rev. 2003, 103, 1, 71–168Publication Date (Web):December 12, 2002Publication History Received20 December 2001Published online12 December 2002Published inissue 1 January 2003https://pubs.acs.org/doi/10.1021/cr960134ohttps://doi.org/10.1021/cr960134oresearch-articleACS PublicationsCopyright © 2003 American Chemical SocietyRequest reuse permissionsArticle Views12085Altmetric-Citations395LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Anions,Halogens,Ions,Reaction products,Substitution reactions Get e-Alerts
Key Findings
1
Mechanistic understanding of substitution-by-electron-transfer unifies observations involving anions, halogens, and ionic reaction products.
2
Nucleophilic substitution reactions can proceed via electron transfer mechanisms rather than classical bimolecular pathways.
3
The article compiles and analyzes experimental and theoretical studies to establish electron-transfer pathways as important alternatives to traditional substitution mechanisms.
4
The review synthesizes evidence that electron transfer plays a key role in many nucleophilic substitution processes across different substrates and conditions.
Research Object
Nucleophilic substitution reactions proceeding via electron-transfer mechanisms (electron-transfer-mediated nucleophilic substitutions)
Research Subject
Mechanistic aspects and outcomes of nucleophilic substitution when initiated or mediated by electron transfer, including electron-transfer pathways, intermediates, kinetics, and product distributions
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2002-12-12
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