Halosulfonamidation of camphene: chemo and stereoselectivity, rearrangement, solvent interception, heterocyclization
Галосульфонамидирование кампена: хемо- и стереоселективность, перегруппировка, перехват растворителя, гетероциклизация
2024-01-01
SCID: 54.1/j3m39b5m
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N-sulfonyl camphanecamphenechemo- and stereoselectivityhalosulfonamidationheterocyclizationisocamphaneoxidantsrearrangementsolvent incorporationsulfonamides
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Abstract (AI)
Camphene reacts with sulfonamides in the presence of oxidants to give N -sulfonyl derivatives of camphane or isocamphane with or without solvent incorporation depending on the reagent and the ratio of the reactants.
Key Findings
1
Camphene reacts with sulfonamides in the presence of oxidants to yield N-sulfonyl derivatives of camphane or isocamphane.
2
Solvent incorporation into the products can occur or be avoided depending on the reagent and reactant ratio.
3
The product chemo- and stereoselectivity (camphane versus isocamphane) depends on the choice of oxidant and reagent conditions.
4
The reaction pathway involves rearrangement and allows for heterocyclization under certain conditions.
Research Object
Reaction of camphene with sulfonamides in the presence of oxidants (halosulfonamidation system)
Research Subject
Chemo- and stereoselectivity, rearrangement pathways, solvent incorporation (interception), and heterocyclization outcomes of the halosulfonamidation of camphene
Publication Details
Publication Date
2024-01-01
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