Thermodynamics of electrolytes. I. Theoretical basis and general equations
Термодинамика электролитов. I. Теоретические основы и общие уравнения
1973-01-01
SCID: 54.1/jgb93pd7
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Debye-Hückel termGuggenheim equationsThermodynamics of electrolytesactivity coefficientosmotic coefficient
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermodynamics of electrolytes. I. Theoretical basis and general equationsKenneth S. PitzerCite this: J. Phys. Chem. 1973, 77, 2, 268–277Publication Date (Print):January 1, 1973Publication History Published online1 May 2002Published inissue 1 January 1973https://pubs.acs.org/doi/10.1021/j100621a026https://doi.org/10.1021/j100621a026research-articleACS PublicationsRequest reuse permissionsArticle Views10088Altmetric-Citations2891LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts
Key Findings
1
Appropriate differentiation of the subdivided Debye–Hückel series yields correct but very complex formulas for osmotic and activity coefficients.
2
Scatchard and co-workers extended and elaborated Guggenheim equations for electrolyte thermodynamics.
3
The Debye–Hückel term in the governing equation is subdivided into a series of terms with different coefficients of I^(1/2) corresponding to different closest-approach distances of solute components.
Research Object
Electrolyte solutions (thermodynamic description of electrolytes)
Research Subject
Theoretical basis and general thermodynamic equations for electrolytes, including extensions of Guggenheim equations and refined Debye–Hückel contributions to osmotic and activity coefficients
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1973-01-01
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