Hypervalent iodine(III) reagents in organic synthesis
Гипервалентные реагенты йода(III) в органическом синтезе
2009-02-21
SCID: 54.1/k7kk8xd3
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hypervalent iodine(III) reagentsorganic synthesisorganoiodine(III) catalysisoxidative transformationsrecyclable reagents
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Abstract (AI)
This review summarizes the chemistry of hypervalent iodine(III) compounds with emphasis of their synthetic applications.The preparation and reactions of (difluoroiodo)arenes, (dichloroiodo)arenes, iodosylarenes, [bis(acyloxy)iodo]arenes, and aryliodine(III) organosulfonates are overviewed.Application of these reagents allows mild and highly selective oxidative transformations in a facile and environmentally friendly manner.Some of these useful transformations can be carried out using organoiodine(III) compounds as catalysts or recyclable reagents.
Key Findings
1
Applications include (difluoroiodo)arenes, (dichloroiodo)arenes, iodosylarenes, bis(acyloxy)iodoarenes, and aryliodine(III) organosulfonates.
2
Hypervalent iodine(III) reagents enable mild, highly selective oxidative transformations in a facile and environmentally friendly manner.
3
Some organoiodine(III) compounds function as catalysts or recyclable reagents, improving the sustainability of oxidative synthesis.
4
The review surveys the preparation and synthetic reactions of major hypervalent iodine(III) reagent classes.
Research Object
hypervalent iodine(III) compounds and reagents in organic synthesis
Research Subject
their preparation, reactions, and synthetic applications, including mild and selective oxidative transformations and their use as catalysts or recyclable reagents
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2009-02-21
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