Current Flow Mechanisms and Photoelectric Properties of Solar Cells Based on p-CdTe-n-CdS and p-CdTe-n-CdSe Heterostructures with Deep Impurity Levels
Механизмы протекания тока и фотоэлектрические свойства солнечных элементов на основе гетероструктур p-CdTe–n-CdS и p-CdTe–n-CdSe с глубокими уровнями примесей
2025-01-01
SCID: 54.1/kkcu36mb
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deep impurity levelsnear-infrared spectral region 0.4–3.0 eVp-CdTe-n-CdS heterojunctionp-CdTe-n-CdSe heterojunctionphotoconversion efficiency 0.7–0.8 eV?reverse tunneling currentsurface state density N=3·10^11 cm^-2thermionic forward currenttunneling of thermally excited electrons
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Abstract (AI)
In this paper, we consider the mechanisms of the flow current and photoelectric properties of solar cells manufactured on the basis of strongly mismatched semiconductor p-CdTe-n-CdS and p-CdTe-n-CdSe heterojunctions with a low density of surface states N=3·1011sm-2. It was found that the forward current in heterojunctions is due to tunneling of thermally excited electrons, and at large forward biased currents, thermionic nature. The reverse current of such structures has a tunneling nature. It is shown that the structures have a photoconversion efficiency of 0.7 and 0.8 el/sq in the spectral region of 0.4 and 3.0 eV in the near-infrared region of the spectrum.
Key Findings
1
At large forward biased currents the forward current becomes thermionic in nature
2
Forward current in p-CdTe-n-CdS and p-CdTe-n-CdSe heterojunctions is governed by tunneling of thermally excited electrons at low/moderate forward bias
3
Reverse current in these strongly mismatched heterostructures has a tunneling nature
4
Solar-cell structures with low surface-state density (N = 3·10^11 cm^-2) exhibit photoconversion efficiencies of 0.7 and 0.8 el/sq in the spectral region from 0.4 to 3.0 eV (near-infrared)
Research Object
Solar cells based on strongly mismatched p-CdTe/n-CdS and p-CdTe/n-CdSe heterojunctions with deep impurity levels and low surface-state density
Research Subject
Current flow mechanisms (forward tunneling of thermally excited electrons, thermionic behavior at high forward bias, tunneling reverse current) and photoelectric/photoconversion properties (spectral photoconversion efficiency in the 0.4–3.0 eV range)
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2025-01-01
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