Synthesis of benzotriazole derivatives and their effect on antioxidant properties of synthetic lubricant oil

Синтез производных бензотриазола и их влияние на антиокислительные свойства синтетического смазочного масла
Insitute of Chemistry of Additives of after acad. A.M. Guliyev of Ministry of Science and Education of Azerbaijan, A.А. Gadirov, E.A. Nagiyeva, В. М. Фарзалиев
2023-01-01

antioxidant additivesbenzotriazole derivativesphenyl-α-naphthylaminesynthetic lubricating oilthermooxidative stability
New N-(aryl(alkylaryl)aminomethyl)-1,2,3-benzotriazoles have been synthesized and their antioxidant properties in the composition of synthetic lubricating oil have been studied. The structure of the obtained compounds was confirmed by IR and NMR spectroscopy. N-(aryl(alkylaryl)aminomethyl)-1,2,3-benzotriazoles were investigated as additives to synthetic lubricating oils. An ester of pentaerythritol and synthetic fatty acids of the C5-C9 fraction (PEE) was used as a synthetic oil. Effect of synthesized compounds on thermooxidative the stability of synthetic lubricating oil was studied standard method volume oxidation according to GOST 236797-79, for 20 hours at a temperature of 225 ° C, in the presence of steel, aluminum and copper plates. It has been shown that the obtained antioxidants noticeably delay the process of oxidation of ester oils and are superior in efficiency to the well-known inhibitor phenyl-α naphthylamine.
1
New N-(aryl(alkylaryl)aminomethyl)-1,2,3-benzotriazole derivatives were synthesized and structurally confirmed using IR and NMR spectroscopy.
2
The benzotriazole derivatives noticeably delayed oxidation of the ester-based lubricating oil and outperformed the established inhibitor phenyl-α-naphthylamine.
3
The synthesized benzotriazoles were evaluated as antioxidant additives in pentaerythritol ester synthetic lubricating oil containing C5–C9 synthetic fatty acid residues.
4
Thermooxidative stability was assessed by the standard volume oxidation method for 20 hours at 225 °C in contact with steel, aluminum, and copper plates.

Synthetic lubricating oil based on pentaerythritol ester of C5–C9 synthetic fatty acids containing N-(aryl(alkylaryl)aminomethyl)-1,2,3-benzotriazole additives

The antioxidant activity of synthesized benzotriazole derivatives and their effect on the thermooxidative stability and oxidation-inhibition efficiency of synthetic ester oil compared with phenyl-α-naphthylamine

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2023-01-01
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Insitute of Chemistry of Additives of after acad. A.M. Guliyev of Ministry of Science and Education of Azerbaijan
A.А. Gadirov
E.A. Nagiyeva
В. М. Фарзалиев
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