Physical properties of bioplastic agar/chitosan blend

Физические свойства биопластика на основе смеси агара и хитозана
Agusman Agusman, Dina Fransiska, Murdinah, T H Wahyuni, Hari Eko Irianto, P Priambudi, Fateha, Akbar Hanif Dawam Abdullah, R D Nissa, Bonita Firdiana, Nurhayati Nurhayati
2022-02-01

agar/chitosan blendbioplasticrheomix processtensile strengthwater vapor transmission rate
Abstract Thermoplastic agar/chitosan blend was prepared by a rheomix process, and the effect of concentration agar: chitosan on the material properties forms were investigated. This research aimed to observe the physical properties of bioplastic agar/chitosan produced through rheomix. Bioplastic was produced by mixing 65 % solid material (agar: chitosan) and 35% glycerol, the ration through the melting process at an initial temperature of 100°C. The weight ratio of agar : chitosan was 65% : 0% (F0/control), 52% : 13% (F1), 39 % : 26% (F2), 26 %: 39% (F3). The tensile strength and elongation of bioplastic were decrees with a higher chitosan concentration. The color and the opacity of bioplastic were affected by the ratio of agar: chitosan. The moisture content and the water vapor transmission rate (WVTR) of bioplastic were increased by increasing the chitosan ratio. The SEM micrograph of bioplastic showed that the blend agar and chitosan seem to have a rough and inhomogeneous surface than pure bioplastic agar. The best blend was bioplastic with agar: chitosan 52%: 13% (F1), which have properties of : tensile strength 4.95 ± 0.56 MPa, elongation at break 34.94 ± 0.99 %, moisture content 15.33 ± 0.43%, WVTR 3259.39 ± 28.12 g/m2.24 h.
1
Agar/chitosan bioplastics were produced by rheomix processing using 65% agar/chitosan solids and 35% glycerol at an initial melting temperature of 100°C.
2
Increasing the chitosan proportion decreased tensile strength and elongation while increasing moisture content and water vapor transmission rate.
3
The 52% agar:13% chitosan formulation was identified as the best blend, with tensile strength of 4.95 ± 0.56 MPa and elongation at break of 34.94 ± 0.99%.
4
The agar-to-chitosan ratio significantly affected bioplastic color and opacity, and blended samples had rougher, more inhomogeneous surfaces than pure agar bioplastic.
5
The best blend had 15.33 ± 0.43% moisture content and a water vapor transmission rate of 3259.39 ± 28.12 g/m²·24 h.

Thermoplastic agar/chitosan bioplastic blends with varying agar-to-chitosan ratios

The effects of agar-to-chitosan composition on the physical, mechanical, optical, moisture, water-vapor barrier, and morphological properties of the bioplastic

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2022-02-01
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Authors
Agusman Agusman
Dina Fransiska
Murdinah
T H Wahyuni
Hari Eko Irianto
P Priambudi
Fateha
Akbar Hanif Dawam Abdullah
R D Nissa
Bonita Firdiana
Nurhayati Nurhayati
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