Introducing I − /formic acid as a green reagent for the reduction of sulfinates and sulfoxides
Введение I−/муравьиной кислоты в качестве экологически безопасного реагента для восстановления сульфинатов и сульфоксидов
2023-01-01
SCID: 54.1/n6srvhst
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I−/formic acidformic acidiodide catalystreduction of sulfoxides and sulfinatessulfinyl group deoxygenation
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Abstract (AI)
A sustainable method using formic acid and iodide as a catalyst for sulfinyl group deoxygenation in sulfoxides and sulfinates. Formic acid networks facilitate sulfinyl reduction.
Key Findings
1
Formic acid combined with iodide functions as a sustainable reagent system for deoxygenation of sulfinyl groups in sulfoxides and sulfinates.
2
Formic acid networks (hydrogen-bonding/proton-donor interactions) facilitate the sulfinyl reduction mechanism.
3
Iodide acts catalytically in the reduction, enabling use of catalytic rather than stoichiometric halide.
4
The method offers a greener alternative for reducing sulfinyl-containing substrates compared to conventional reagents.
Research Object
Sulfoxides and sulfinates undergoing sulfinyl group deoxygenation using formic acid and iodide
Research Subject
Use of formic acid and iodide (I−/formic acid) as a green reagent/catalytic system to promote sulfinyl group reduction/deoxygenation and the role of formic acid networks in facilitating the reaction
Publication Details
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2023-01-01
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