Oxidase‐Like Activity of Polymer‐Coated Cerium Oxide Nanoparticles

Оксидазоподобная активность покрытых полимером наночастиц оксида церия
Santimukul Santra, J. Manuel Perez, Charalambos Kaittanis, Atul Asati, Sudip Nath
2009-01-07

TMB colorimetric detectioncerium oxide nanoparticlesenzyme-linked immunosorbent assayoxidase-like activitypolymer-coated nanoparticles
Inorganic enzyme? Ceria nanoparticles exhibit unique oxidase-like activity at acidic pH values. These redox catalysts can be used in immunoassays (ELISA) when modified with targeting ligands (see picture; light blue and yellow structures are nanoparticles with attached ligands). This modification allows both for binding and for detection by the catalytic oxidation of sensitive colorimetric dyes (e.g. TMB).
1
Cerium oxide nanoparticles exhibit oxidase-like redox catalytic activity, particularly under acidic pH conditions.
2
Nanoparticle-mediated oxidation of colorimetric substrates such as TMB provides a detectable assay signal.
3
Polymer coating and attachment of targeting ligands enable cerium oxide nanoparticles to combine specific binding with catalytic detection.
4
The modified nanoparticles can be applied in ELISA immunoassays as inorganic enzyme-like labels.

polymer-coated cerium oxide nanoparticles

oxidase-like activity and its use for catalytic colorimetric detection in ELISA under acidic conditions

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Publication Date
2009-01-07
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Authors
Santimukul Santra
J. Manuel Perez
Charalambos Kaittanis
Atul Asati
Sudip Nath
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