The 16 and 18 electron rule in organometallic chemistry and homogeneous catalysis
Правило 16 и 18 электронов в органометаллической химии и гомогенном каталозе
1972-01-01
SCID: 54.1/pzjgca6x
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16 and 18 electron rulehomogeneous catalysisorganometallic chemistry
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Key Findings
1
It highlights the practical importance of understanding electron-counting rules for predicting stability and reactivity of organometallic complexes used in catalysis.
2
It identifies how deviations from the 18-electron rule, particularly 16-electron species, are common and critically influence catalytic activity.
3
The paper examines the 16- and 18-electron rules as fundamental principles governing organometallic chemistry and homogeneous catalysis.
4
The review discusses mechanistic implications of electron counts for ligand coordination, reaction pathways, and catalyst design.
Research Object
Organometallic complexes relevant to homogeneous catalysis
Research Subject
Application and implications of the 16- and 18-electron rules for electronic structure, stability, and reactivity in organometallic chemistry and homogeneous catalysis
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1972-01-01
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