Representation of the Viscosity of Molten Alloy as a Function of the Composition and Temperature

Представление вязкости расплавленного сплава как функции состава и температуры
Yuzuru Sato
2011-11-01

logarithmic additivitymolten alloy viscositynickel-based superalloysoscillating viscometerseparation of variables
Although the viscosity of molten metal is very important, the measurement is considerably difficult for high temperature melts. The author's group has developed an oscillating viscometer for high temperature metal. The prediction of the viscosity behavior of the alloys is most useful task because the experimental data acquisition is not easy. In the prediction process, important issue is the composition and temperature dependence. The author has found that the additivity of the logarithmic viscosity was dominant criteria on the composition dependence based on the result of Fe–Si binary melt. Therefore, the logarithmic additivity was adapted to some nickel based super-alloys which were multi component systems. The viscosities of nickel based five binary melts were measured for the representation of the viscosities of super-alloys. The formulation was done by using the separation of variables method. The pre-exponential term and the activation energy were separately approximated as a function of the composition. The results of the approximation successfully represented the viscosities of molten super-alloys.
1
A separation-of-variables formulation approximated the pre-exponential factor and activation energy independently as functions of composition.
2
High-temperature viscosity measurements are difficult, motivating prediction methods for molten alloys across composition and temperature.
3
Results for Fe–Si binary melts showed that logarithmic viscosity additivity is the dominant criterion for representing composition dependence.
4
The logarithmic-additivity approach was extended to multicomponent nickel-based superalloys using measurements from five nickel-based binary melts.
5
The resulting model successfully represented the viscosities of molten nickel-based superalloys.

molten nickel-based super-alloys and their binary melts

composition- and temperature-dependent viscosity, including logarithmic additivity and the composition dependence of the pre-exponential term and activation energy

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2011-11-01
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Yuzuru Sato
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