Cellulosic substrates for removal of pollutants from aqueous systems: A review. 1. Metals

Целлюлозные субстраты для удаления загрязнителей из водных систем: обзор. 1. Металлы
Syed Hadi Hasan, Martin A. Hubbe, Joel J. Ducoste
2011-05-01

biomass modificationbiosorbentscellulosic substratesheavy metal removalmechanistic adsorption models
Recent years have seen explosive growth in research concerning the use of cellulosic materials, either in their as-recieved state or as modified products, for the removal of heavy metal ions from dilute aqueous solutions. Despite highly promising reports of progress in this area, important questions remain. For instance, it has not been clearly established whether knowledge about the composition and structure of the bioadsorbent raw material is equally important to its availability at its point of use. Various physical and chemical modifications of biomass have been shown to boost the ability of the cellulose-based material to bind various metal ions. Systems of data analysis and mechanistic models are described. There is a continuing need to explain the mechanisms of these approaches and to determine the most effective treatments. Finally, the article probes areas where more research is urgently needed. For example, life cycle analysis studies are needed, comparing the use of renewable biosorbents vs. conventional means of removing toxic metal ions from water.
1
Both unmodified (as-received) and chemically/physically modified cellulosic substrates can bind various metal ions, with modifications shown to boost binding ability.
2
Data-analysis systems and mechanistic models exist, but mechanisms of adsorption and the most effective treatments require further explanation and validation.
3
Research on cellulosic materials for removing heavy metal ions from dilute aqueous solutions has grown explosively in recent years.
4
The relative importance of bioadsorbent composition/structure versus local availability at point of use remains unclear and unresolved.
5
Urgent research needs include life cycle analysis comparing renewable biosorbents with conventional methods for removing toxic metal ions from water.

Cellulosic substrates (native and modified biomass-based adsorbents) used for removal of heavy metal ions from dilute aqueous solutions

Effectiveness and mechanisms of metal ion removal including how composition, structure, and physical/chemical modifications of cellulosic substrates influence adsorption performance, treatment optimization, data-analysis models, and gaps such as life-cycle comparisons with conventional removal methods

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2011-05-01
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Syed Hadi Hasan
Martin A. Hubbe
Joel J. Ducoste
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