A comprehensive study on the fire resistance properties of ultra-fine ceramic waste-filled high alkaline white cement paste composites for progressing towards sustainability

Комплексное исследование огнестойких свойств композитных паст из белого высокощелочного цемента с наполнителем из ультратонкого керамического вторсырья в контексте устойчивого развития
M. A. Abdelzaher, Asmaa S. Hamouda, Ibrahim M. El-Kattan
2023-12-13

XRF XRD FTIR SEMcompressive strengthfire resistancehigh-alkaline white cementultra-fine ceramic waste
The most practical sustainable development options to safeguard the local ecology involve reducing the use of raw materials and guaranteeing proper recycling of the principal destroyed solid wastes. Preventing the creation of hazardous waste and the subsequent pollution that results from improper disposal is a top priority. Based on this, the study's authors recommend reusing the ultra-fine ceramic shards (CW). High-alkaline white cement (WC) has been partially replaced by ultra-fine CW because it is a cheaper, more abundant, and more lasting environmental material used in the production of trendy blended white cement pastes composites. In this context, we look at ultra-fine CW, a material that has been suggested for use as a hydraulic filler due to its high performance, physicomechanical qualities, and durability. XRF, XRD, FTIR, and SEM measurements are used to characterize the microstructure, thermal characteristics, and thermodynamics. Because of the effect of ultra-fine ceramic waste, the firing test reduces the mechanical strength by default, but with active filler, decreases slowly and increase its physicomechanical features and compressive strength compared to the control sample (WC), setting a new benchmark. The maximum amount of crystallization formed in the presence of ultra-fine ceramic waste in WC-matrix, resulting in a decrease in total porosity and early cracking. Together, the improved workability and energy-saving features of cement blends with ultra-fine ceramic waste, reflect their economic and environmental benefits, which may reduce building costs and boost the durability of the raw materials used in the mix.
1
Firing tests show that while the presence of ultra-fine ceramic waste tends to reduce mechanical strength by default, the active filler effect causes a slower decrease and net improvement versus control samples.
2
Microstructural, thermal, and thermodynamic characterization (XRF, XRD, FTIR, SEM) supports the beneficial role of ultra-fine CW in enhancing performance and durability.
3
Partial replacement of high-alkaline white cement (WC) with ultra-fine ceramic waste (CW) produces blended white cement pastes with improved physicomechanical properties and compressive strength compared to the WC control.
4
Ultra-fine CW acts as an effective hydraulic filler, promoting maximal crystallization in the WC matrix, which decreases total porosity and reduces early cracking.
5
Using ultra-fine ceramic waste improves workability and energy-saving features of cement blends, offering economic and environmental benefits by lowering building costs and enhancing sustainability.

Ultra-fine ceramic waste-filled high-alkaline white cement paste composites

Fire resistance properties and related physicomechanical, microstructural, thermal, porosity, crystallization, workability, and compressive-strength behavior of those composites when partially replacing white cement with ultra-fine ceramic waste

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2023-12-13
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Authors
M. A. Abdelzaher
Asmaa S. Hamouda
Ibrahim M. El-Kattan
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