Synthesis and structure of complex compounds of lanthanum, europium, and scandium iodides with antipyrine
Синтез и строение комплексных соединений иодидов лантана, европия и скандия с антипирином
2009-04-01
SCID: 54.1/tqgpfxpu
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X-ray single-crystal diffractionantipyrine complexescoordination through carbonyl oxygeneuropium iodidelanthanum iodideoctahedral coordinationscandium iodide
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Abstract (AI)
Synthesis and X-ray single-crystal diffraction study of antipyrine complexes of lanthanum, europium, and scandium iodides were performed. In all compounds, the inner coordination sphere of the complex cation is an octahedron formed by antipyrine molecules coordinated through the oxygen atoms of the C=O groups.
Key Findings
1
Antipyrine complexes of lanthanum, europium, and scandium iodides were successfully synthesized.
2
Antipyrine coordinates to the metal centers through the oxygen atoms of its C=O groups.
3
In all studied compounds, the complex cation's inner coordination sphere is an octahedron formed by antipyrine molecules.
4
X-ray single-crystal diffraction was used to determine the structures of these complexes.
Research Object
Antipyrine complexes of lanthanum, europium, and scandium iodides (single crystals)
Research Subject
Synthesis and crystal structure (inner coordination sphere: octahedral coordination by antipyrine via C=O oxygen atoms) characterized by X-ray single-crystal diffraction
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2009-04-01
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