Disadvantage of interaction between cellulose and a classical hydrogen-bonded ferroelectric of dimethylammonium aluminum sulfate hexahydrate
Недостаток взаимодействия между целлюлозой и классическим водородсвязывающимся ферроэлектриком диметиламмоний алюминиевого сульфата гексагидрата
2023-10-26
SCID: 54.1/vs9uvjw6
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cellulose nanoparticlesdepression of ferroelectricitydielectric relaxationdimethylammonium aluminum sulphate hexahydrateferroelectric metal-organic framework
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Abstract (AI)
Despite the state-of-the-art advantages of cellulose in improving the quality of electrical and electronic materials, this natural material does not always bring positive effects. The present work aims at filling this gap. For this purpose, a novel ferroelectric nanocomposite based on a classical ferroelectric metal-organic framework of dimethylammonium aluminum sulphate hexahydrate with a dielectric inclusion of cellulose nanoparticles was synthesized. The study on structure and dielectric properties revealed that the cellulose caused a strong depression of ferroelectricity at temperatures of lower than 115 K when interacting with functional groups of the ferroelectric component.
Key Findings
1
A novel ferroelectric nanocomposite was synthesized from dimethylammonium aluminum sulfate hexahydrate with dielectric cellulose nanoparticles inclusion.
2
Cellulose nanoparticles interacting with functional groups of the ferroelectric component caused a strong depression of ferroelectricity below 115 K.
3
The cellulose inclusion negatively affected dielectric and polarization switching properties at temperatures lower than 115 K.
4
The work identifies a disadvantageous interaction between cellulose and a classical hydrogen-bonded ferroelectric framework, highlighting cellulose can harm ferroelectric performance.
Research Object
Nanocomposite consisting of dimethylammonium aluminum sulfate hexahydrate ferroelectric metal-organic-framework with dielectric inclusion of cellulose nanoparticles
Research Subject
Interaction-induced suppression of ferroelectricity and altered dielectric/polarization-switching behavior (strong depression of ferroelectricity below ~115 K) caused by cellulose–ferroelectric component interactions
Publication Details
Publication Date
2023-10-26
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