Simultaneous crystallization of an in situ formed conjugated polymer and inorganic matrix for structure solving
Одновременная кристаллизация конъюгированного полимера, образовавшегося in situ, и неорганической матрицы для решения структуры
2017-01-01
SCID: 54.1/y96dh3nx
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bromoplumbate matrixconjugated polymer–inorganic compositecrystal structure solvingencapsulation of conjugated polymer chainsin situ crystallization
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Abstract (AI)
Here, we have, for the first time, reported the crystal structure of a conjugated polymer-inorganic composite by encapsulating conjugated polymer chains into a porous bromoplumbate matrix. The photoelectrochemical studies indicate that the as-obtained hybrid displays a p-type semiconductor behavior under visible-light illumination.
Key Findings
1
Encapsulation into a bromoplumbate matrix provides a method to determine polymer chain arrangement via crystallography
2
First reported crystal structure of a conjugated polymer–inorganic composite obtained by encapsulating conjugated polymer chains into a bromoplumbate matrix
3
Simultaneous crystallization approach enables structure solving of an in situ formed conjugated polymer within an inorganic matrix
Research Object
Conjugated polymer–bromoplumbate inorganic composite formed by in situ encapsulation of conjugated polymer chains into a bromoplumbate matrix
Research Subject
Simultaneous crystallization enabling determination of the crystal structure of the conjugated polymer–inorganic composite
Publication Details
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2017-01-01
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