Photoinduced Postsynthetic Polymerization of a Metal–Organic Framework toward a Flexible Stand‐Alone Membrane

Metal-organic frameworks (MOFs) are a promising class of nanoporous polymeric materials. However, the processing of such fragile crystalline powders into desired shapes for further applications is often difficult. A photoinduced postsynthetic polymerization (PSP) strategy was now employed to covalently link MOF crystals by flexible polymer chains, thus endowing the MOF powders with processability and flexibility. Nanosized UiO-66-NH2 was first functionalized with polymerizable functional groups, and its subsequent copolymerization with monomers was easily induced by UV light under solvent-free and mild conditions. Because of the improved interaction between MOF particles and polymer chains, the resulting stand-alone and elastic MOF-based PSP-derived membranes possess crack-free and uniform structures and outstanding separation capabilities for Cr(VI) ions from water.