Identification and Evaluation of High-Performance EOR Surfactants

Abstract We report results for a number of promising EOR surfactants based upon a fast, low-cost laboratory screening process that is highly effective in selecting the best surfactants to use with different crude oils. Initial selection of surfactants is based upon desirable surfactant structure. Phase behavior screening helps to quickly identify favorable surfactant formulations. Salinity scans are conducted to observe equilibration times, microemulsion viscosity, oil and water solubilization ratios and interfacial tension. Co-surfactants and co-solvents are included to minimize gels, liquid crystals and macroemulsions and to promote rapid equilibration to low-viscosity microemulsions. Branched alcohol propoxy sulfates, internal olefin sulfonates, and branched alpha olefin sulfonates have been identified as good EOR surfactants using this screening process. These surfactants are available at low cost and are compatible with both polymers and alkali such as sodium carbonate and thus are good candidates for both surfactant- polymer and alkali-surfactant-polymer EOR processes. One of the best formulations was tested in both sandstone and dolomite cores and found to give excellent oil recovery and low surfactant retention.