Ultralow-loading platinum-cobalt fuel cell catalysts derived from imidazolate frameworks

Jianxin Zou, Wenjiang Ding, Maria K. Y. Chan, Joseph Kubal, Lina Chong, Jianguo Wen, Fatih G. Sen, Jeffery P. Greeley, Heather M. Barkholtz, Di‐Jia Liu
2018-11-08

SCID:  54.1/zrh54qap
Combine and conquer Platinum (Pt)–group metals, which are scarce and expensive, are used for the demanding oxygen reduction reaction (ORR) in hydrogen fuel cells. One competing approach for reducing their use is to create nanoparticles with earth-abundant metals to increase their activity and surface area; another is to replace them with metals such as cobalt (Co) in carbide or nitride sites. Chong et al. thermally activated a Co metal-organic framework compound to create ORR-active Co sites and then grew PtCo alloy nanoparticles on this substrate. The resulting catalyst had high activity and durability, despite its relatively low Pt content. Science , this issue p. 1276
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2018-11-08
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Jianxin Zou
Wenjiang Ding
Maria K. Y. Chan
Joseph Kubal
Lina Chong
Jianguo Wen
Fatih G. Sen
Jeffery P. Greeley
Heather M. Barkholtz
Di‐Jia Liu
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