Carbon materials for ion-intercalation involved rechargeable battery technologies
Углеродные материалы для технологий перезаряжаемых батарей с интеркаляцией ионов
2020-12-21
SCID: 54.1/h954b6b2
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Al-ion batteriesanion intercalationcarbon materialsdual-ion batteriesion intercalation
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Abstract (AI)
) at low redox potentials, carbon materials can serve as ideal anodes for 'Rocking-Chair' alkali metal-ion batteries. Meanwhile, acceptor-type intercalation of anions into graphitic carbon materials has also been revealed to be a facile, reversible process at high redox potentials. Based on anion-intercalation graphitic carbon materials, a number of dual-ion battery and Al-ion battery technologies are experiencing booming development. In this review, we summarize the significant advances of carbon materials in terms of the porous structure, chemical composition, and interlayer spacing control. Fundamental mechanisms of carbon materials as the cation host and anion host are further revisited by elaborating the electrochemistry, intercalant effect, and intercalation form. Subsequently, the recent progress in the development of novel carbon nanostructures and carbon-derived energy storage devices is presented with particular emphasis on correlating the structures with electrochemical properties as well as assessing the device configuration, electrochemical reaction, and performance metric. Finally, perspectives on the remaining challenges are provided, which will accelerate the development of new carbon material concepts and carbon-derived battery technologies towards commercial implementation.
Key Findings
1
Anion intercalation into graphitic carbon is a facile and reversible high-redox-potential process enabling dual-ion and aluminum-ion batteries.
2
Carbon materials function as ideal low-redox-potential anodes for rocking-chair alkali metal-ion batteries.
3
Cation and anion hosting mechanisms depend on electrochemistry, intercalant effects, and the structural form of intercalation.
4
Controlling carbon porosity, chemical composition, and interlayer spacing is central to tuning ion-intercalation behavior and electrochemical performance.
5
Recent carbon nanostructures and carbon-derived devices are evaluated by correlating material structures with electrochemical properties, device configurations, reactions, and performance metrics; remaining challenges affect commercialization.
Research Object
Carbon materials used as cation and anion hosts in rechargeable alkali-metal-ion, dual-ion, and Al-ion batteries
Research Subject
The relationships between carbon-material structure and electrochemical intercalation mechanisms, properties, and battery performance
Publication Details
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2020-12-21
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