Re-designing the substrate binding pocket of laccase for enhanced oxidation of sinapic acid

Перепроектирование кармана связывания субстрата лакказы для усиления окисления синаповой кислоты
Vı́ctor Guallar, Ángel T. Martı́nez, Isabel Pardo, Susana Camarero, Francisco J. Medrano, Patrizia Gentili, Emanuele Monza, Maria Fátima Lucas, Gerard Santiago, C. GALLI
2015-12-29

high redox potentialiterative saturation mutagenesislaccasesinapic acid oxidationsubstrate binding pocket
Iterative saturation mutagenesis was performed over six residues delimiting the substrate binding pocket of a high redox potential chimeric laccase with the aim of enhancing its activity over sinapic acid, a lignin-related phenol of industrial interest.
1
Iterative saturation mutagenesis targeted six residues delimiting the substrate-binding pocket of a high-redox-potential chimeric laccase.
2
The abstract describes substrate-pocket redesign but provides no specific mutations, activity improvements, or comparative performance data.
3
The engineering strategy aimed to enhance laccase oxidation activity toward sinapic acid, an industrially relevant lignin-related phenol.

high-redox-potential chimeric laccase substrate-binding pocket

enhanced catalytic oxidation of sinapic acid through substrate-binding pocket redesign

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2015-12-29
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Authors
Vı́ctor Guallar
Ángel T. Martı́nez
Isabel Pardo
Susana Camarero
Francisco J. Medrano
Patrizia Gentili
Emanuele Monza
Maria Fátima Lucas
Gerard Santiago
C. GALLI
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