High Weight Fraction Surfactant Solubilization of Single-Wall Carbon Nanotubes in Water

Солюбилизация одностенных углеродных нанотрубок в воде с использованием поверхностно-активного вещества при высокой массовой доле
Mohammad F. Islam, Eugenio Rojas, D. M. Bergey, A. T. Charlie Johnson, Arjun G. Yodh
2003-01-16

aqueous solubilizationatomic force microscopynanotube bundle exfoliationsingle-wall carbon nanotubessodium dodecylbenzene sulfonate
We report a simple process to solubilize high weight fraction single-wall carbon nanotubes in water by the nonspecific physical adsorption of sodium dodecylbenzene sulfonate. The diameter distribution of nanotubes in the dispersion, measured by atomic force microscopy, showed that even at 20 mg/mL ∼63 ± 5% of single-wall carbon nanotube bundles exfoliated into single tubes. A measure of the length distribution of the nanotubes showed that our dispersion technique reduced nanotube fragmentation.
1
At a concentration of 20 mg/mL, approximately 63 ± 5% of single-wall carbon nanotube bundles exfoliated into individual tubes.
2
Atomic force microscopy was used to characterize nanotube diameter distributions in the aqueous dispersion.
3
Sodium dodecylbenzene sulfonate physically adsorbs nonspecifically to solubilize high weight fractions of single-wall carbon nanotubes in water.
4
The dispersion process reduced nanotube fragmentation, preserving nanotube length more effectively.

Single-wall carbon nanotubes solubilized in water using sodium dodecylbenzene sulfonate

High-weight-fraction aqueous solubilization, bundle exfoliation, and length-preserving dispersion of single-wall carbon nanotubes

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2003-01-16
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Authors
Mohammad F. Islam
Eugenio Rojas
D. M. Bergey
A. T. Charlie Johnson
Arjun G. Yodh
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